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This MAF lamp marked the first application of a phosphor coating to the outer jacket of a mercury lamp, in an effort to improve its colour rendering properties. The original concept was pioneered by Osram-GEC in 1937 at its Wembley laboratories, where the MA medium pressure mercury lamp had been invented just a few years earlier.
The luminescent material is zinc cadmium sulphide activated by copper, (Zn,Cd)S:Cu. It is stimulated by the 365nm UV-A that is able to pass through the hard glass inner arc tube, and produces a weak orange radiation which boosts the red ratio of the lamp from 1% to about 4%. Since the phosphor loses its efficiency above about 150°C, MAF lamps employ a large bulb. This has an isothermal shape to maintain a low surface temperature when operated in the cap-up position.
One drawback of this phosphor is its yellow body colour, which absorbs the mercury blue lines. Despite its own orange radiation, the net result is a rather unpleasant greenish light. This was partially overcome by adding cadmium and sometimes also zinc to the arc tube, which radiates extra blue lines plus a small amount of red. This helps achieve a whiter appearance, but the colour still leaves a lot to be desired - the chromaticity diagram below illustrates its high CCy co-ordinate. The addition of cadmium also causes about 12% decrease in lamp efficacy. Due to the fact that Cadmium has a much lower vapour pressure than mercury, the addition of that metal to a normal MA mercury arc tube would have very little effect. To help bring its vapour into the plasma the lower end of the arc tube is tapered, to increase its cold spot temperature and vapourise more of the metal additives. |